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The Addition of Tenessy CMC: Enhancing Paper Quality and Achieving Energy Savings & Environmental Protection

What Is CMC?

1. Definition of CMC

CMC is the abbreviation for Sodium Carboxymethyl Cellulose, an important cellulose derivative produced by substituting the hydroxyl groups (-OH) on natural cellulose (such as wood or cotton) molecular chains with carboxymethyl groups (-CH₂COO⁻).

2. Physical Properties of CMC

PropertyDescription
AppearanceWhite or slightly yellow fibrous powder, odorless, tasteless, non-toxic
SolubilityEasily soluble in cold or hot water, forming a transparent viscous solution; insoluble in organic solvents like ethanol or acetone, but soluble in 60% aqueous ethanol or acetone solutions
DensityApproximately 1.050 g/cm³ (15–18℃)
HygroscopicityHygroscopic; must be stored in a cool, dry environment
Thermal StabilityStable to light and heat; viscosity decreases with temperature; discoloration temperature 227℃, carbonization temperature 252℃
pH StabilitySolution stable within pH 2–10; solid precipitates when pH < 2, viscosity decreases when pH > 10

3. Chemical Characteristics & Special Properties

Solution Properties

Solutions are neutral or slightly alkaline with excellent thickening, suspending, emulsifying, film-forming, and water retention capabilities.

Rheological Properties

  • Thixotropy

    High-degree-of-polymerization, low-degree-of-substitution CMC solutions exhibit time-dependent viscosity changes, beneficial for processing flow control.

  • Pseudoplasticity

    Viscosity decreases with increasing shear rate and rapidly recovers after shear cessation, ensuring usage stability.

  • Ionic Crosslinking Capability

    Carboxyl groups on molecular chains can crosslink with metal ions (e.g., Al³⁺) to enhance mechanical properties.

4. Tenessy – A Trustworthy Supplier of Powdered Carboxymethyl Cellulose

  • Direct Factory Procurement – We strictly control production processes, product quality, and all cost factors
  • Strong R&D Capabilities – We customize CMC formulations specifically for your application requirements
  • Consistent Quality – From raw materials to finished products, we implement strict quality control measures
  • Premium Service – Providing technical support and rapid response to ensure your business operates smoothly

Whether you’re looking for industrial-grade carboxymethyl cellulose, CMC for rubber applications, or high-viscosity CMC polymers, we provide the solutions you need.

Detailed Applications of CMC in the Paper Industry

As a multifunctional additive in the paper industry, CMC (Sodium Carboxymethyl Cellulose) primarily leverages its thickening, water retention, dispersing, bonding, and film-forming properties to significantly improve paper quality and production efficiency.

1. Core Mechanism of Action

The carboxymethyl groups (-CH₂COO⁻) on CMC molecular chains can form hydrogen bonds and electrostatic interactions with pulp fibers, fillers, and coating particles, thereby:

  • Enhancing inter-fiber bonding: Forming network structures in wet paper sheets
  • Improving coating water retention: Preventing adhesive migration and improving coating uniformity
  • Optimizing rheological performance: Regulating coating viscosity for high-speed coating processes

2. Primary Application Scenarios

2.1 Wet-End Addition (Internal Addition)

Dosage: Typically 0.3%–1% of oven-dry pulp weight

Functions:

  • Improved retention and drainage: Promotes retention of fillers and fine fibers, reducing losses
  • Enhanced paper strength: Increases tensile strength, burst strength, and folding endurance; particularly suitable for tissue paper, cup paper, and other products requiring wet strength
  • Improved formation: Disperses fibers, prevents flocculation, and ensures more uniform paper sheets
  • Increased sizing efficiency: Synergizes with AKD, ASA and other sizing agents to enhance sizing effectiveness

Applicable Paper Grades:

Newsprint, cultural paper, specialty paper, packaging paper

2.2 Coating Process

Dosage: 0.5%–2% of total coating weight

Functions:

  • Coating water retention agent: Prevents adhesive migration into the base paper, enabling coating solids >70% and reducing drying energy consumption
  • Rheology modifier: Improves coating leveling and printability for high-speed blade/air-knife coating
  • Pigment dispersant: Ensures uniform dispersion of calcium carbonate, kaolin and other pigments, preventing sedimentation
  • Enhanced coating quality: Improves coating adhesion, paper gloss, smoothness, and ink absorption

Product Advantage:

Paper-grade CMC with high etherification and low viscosity provides optimal performance.

2.3 Surface Sizing

Application Method: Used in combination with oxidized starch, PVA, etc.

Functions:

  • Improved surface strength: Enhances resistance to picking and dusting
  • Enhanced printability: Improves uniform ink absorption and dot reproduction
  • Functional properties: Imparts water resistance, oil resistance, and antistatic properties

Applicable Paper Grades:

Coated paper, white board, food packaging paper, art paper

3. Key Advantages of Tenessy Paper-Grade CMC

Advantage DimensionSpecific PerformanceEconomic Value
Increased Machine SpeedHigher coating solids, reduced wet coating moisture, lower drying load15–25% production efficiency increase
Quality ImprovementEnhanced strength, surface smoothness, and printabilityHigher finished product rate, lower re-pulping rate
Cost ReductionReduced adhesive consumption, improved filler retention5–10% overall cost savings
Environmental FriendlinessBiodegradable, reduces hazardous chemical usageMeets green papermaking standards

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Unique Functions of Tenessy CMC Products in Different Fields

1. Viscosity Classification Standard

CMC viscosity is typically measured in 1% aqueous solution at 25℃.

Viscosity GradeViscosity Range (mPa·s)Core Characteristics
Low200–4,000Good fluidity, weak thickening, focused on dispersion & suspension
Medium4,000–6,000Balanced thickening and fluidity, strong versatility
High6,000–12,000Strong adhesion, excellent film-forming, high stability

Note: “Ultra-low viscosity” (<100 mPa·s) products are also used in industrial fields for special dispersion systems.

2. Applications of Low-Viscosity CMC (200–4,000 mPa·s)

Key Features: Excellent fluidity, clean taste, easy dispersion

  • Food Industry
    • Beverages: Fruit juice, protein drinks, lactic acid drinks
    • Sauces: Salad dressings, condiments
    • Ice cream: Prevents ice crystal formation
  • Pharmaceutical & Personal Care
    • Eye drops
    • Oral rinses
    • Skincare products
  • Industrial Fields
    • Detergents
    • Paper
    • Ceramics

3. Applications of Medium-Viscosity CMC (4,000–6,000 mPa·s)

Key Features: Balanced comprehensive performance, widest applicability

  • Food Industry
    • Dairy products
    • Powdered beverages
    • Baked goods
  • Coatings & Construction
  • Oilfield Drilling
    • Drilling fluid modifier

4. Applications of High-Viscosity CMC (6,000–12,000 mPa·s)

Key Features: Strong adhesion, high stability, excellent film-forming

  • Food Industry
    • Meat products
    • Jellies and candies
    • Ice cream
  • Oilfield Drilling
    • Drilling mud
  • Pharmaceutical Products
    • Gum gels
    • Wound dressings
    • Tablet binder
  • High-End Industrial Applications
    • Battery binder
    • Premium coatings
    • Textile sizing

5. Selection Recommendations

Application ScenarioRecommended ViscosityKey Considerations
Clear beveragesLow (<2,000)Clean taste, no cling
Yogurt/dairyMedium (4,000–6,000)Protein stabilization, smooth texture
Meat products/ice creamHigh (>6,000)Strong water retention, anti-melting
Paints/mortarMedium–HighBalance of rheology and workability
Oilfield drillingHigh (>6,000)Wellbore stability, fluid loss control
Pharmaceutical gelsHigh (>8,000)Long-lasting adhesion, film-forming
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